A_V : Comparison to Pitzer's book, p. 99, can be made. Agreement to 3 sig digits Delta_V0: Heat Capacity of Solution per mole of salt (standard states) rxn for the ss heat of soln: NaCl(s) -> Na+(aq) + Cl-(aq) Delta_Vs: Delta volume of Solution per mole of salt rxn for heat of soln: n1 H2O(l,pure) + n2 NaCl(s) -> n2 MX(aq) + n1 H2O(l) Delta_Hs = (n1 h_H2O_bar + n2 h_MX_bar - n1 h_H2O_0 - n2 h_MX_0)/n2 phiV: phiV, calculated from the program, is checked against analytical formula in V_standalone program. (comparison against Pitzer book, p. 97, eqn. 96) T, Pres, Aphi, A_V, Delta_V0, Delta_Vs, Vex, phiV, MolarV, MolarV0 Kelvin, bar, sqrt(kg/gmol),sqrt(kg/gmol)cm3/gmol,cm**3/gmolSalt,cm**3/gmolSalt,cm**3/gmolSoln,cm**3/gmolSalt,cm**3/gmol, cm**3/gmol 273.15, 1.01325, 0.376717, 1.5062, -10.3142, -8.58207, 0.15702, 1.73214, 16.4205, 16.2635 298.15, 1.01325, 0.391447, 1.87435, -10.3142, -8.1587, 0.19539, 2.15551, 16.5003, 16.3049 323.15, 1.01325, 0.410293, 2.37352, -10.3142, -7.58465, 0.24743, 2.72956, 16.6872, 16.4398 348.15, 1.01325, 0.433273, 3.06983, -10.3142, -6.78389, 0.32002, 3.53032, 16.9618, 16.6418 373.15, 1.01418, 0.460559, 4.05167, -10.3142, -5.65477, 0.42237, 4.65945, 17.3246, 16.9022 398.15, 2.32238, 0.492454, 5.4513, -10.3142, -4.04518, 0.56828, 6.26903, 17.7872, 17.2189 423.15, 4.76165, 0.529514, 7.48096, -10.3142, -1.71106, 0.77986, 8.60316, 18.3759, 17.596 448.15, 8.92602, 0.572549, 10.4889, -10.3142, 1.74806, 1.0934, 12.0623, 19.1351, 18.0417 473.15, 15.5493, 0.622769, 15.0764, -10.3142, 7.02378, 1.5717, 17.338, 20.1415, 18.5698 498.15, 25.4972, 0.682036, 22.3389, -10.3142, 15.3757, 2.3287, 25.6899, 21.531, 19.2022 523.15, 39.7617, 0.753389, 34.4316, -10.3142, 29.2824, 3.5894, 39.5966, 23.5634, 19.974 548.15, 59.4639, 0.842213, 56.0339, -10.3142, 54.1252, 5.8413, 64.4394, 26.7856, 20.9443 573.15, 85.879, 0.959258, 98.8138, -10.3142, 103.322, 10.301, 113.637, 32.5242, 22.2232 598.15, 120.51, 1.13023, 198.467, -10.3142, 217.925, 20.689, 228.239, 44.7424, 24.053 623.15, 165.294, 1.43872, 494.888, -10.3142, 558.811, 51.59, 569.125, 78.7661, 27.1758 323.15, 1.01325, 0.410293, 2.37352, -10.3142, -7.58465, 0.24743, 2.72956, 16.6872, 16.4398 Breakdown of Volume Calculation at 323.15 K, 1atm: Species MoleFrac Molal V0 partV (partV - V0) H2O(L) 0.818703 0 18.2334 18.1515 -0.0819526 Na+ 0.0906484 6.146 8.34 10.0749 1.73486 Cl- 0.0906484 6.146 8.34 10.0749 1.73486 NaCl(s) 1 26.9942 26.9942 0